Science

Common mistakes in bonding

8 mistakes learners make with bonding, each one named and explained.

All common mistakes

Conducting needs charged particles that are free to move, whatever the substance is made of.

A metal property given as an explanation

What it looks like

Metals are said to conduct because they are shiny or hard.

Why it happens

The properties of metals are learned as one list, so any of them can stand in for any other.

A worked example

Question. Why metals conduct electricity

A common answer. because they are shiny

The answer. because they have delocalised electrons free to move

Why. Being shiny is a separate consequence of the same structure, not a cause of conduction.

Put the two side by side

Shiny, malleable, conducting: all consequences.
Delocalised electrons: the one cause underneath them.

An explanation has to name the structure, not another property.

An element put on the wrong side of the table

What it looks like

Diamond is described as a metal, or a metal as a non-metal.

Why it happens

Shiny, hard and conducting are all associated with metals, and some non-metals share them.

A worked example

Question. Diamond and graphite

A common answer. diamond is a metal

The answer. both are forms of carbon, a non-metal

Why. Carbon sits on the non-metal side of the table whatever form it takes.

Put the two side by side

A metal conducts and is malleable.
Graphite conducts but shatters, because it is not a metal.

One shared property does not make something a metal. Check the table, not the appearance.

Conduction behaviour matched to the wrong structure

What it looks like

A substance that conducts only when molten or dissolved is identified as simple molecular or giant covalent.

Why it happens

The clue in the question is about states, and the structures were learned as static diagrams.

A worked example

Question. Conducts when molten or dissolved, not when solid

A common answer. a simple molecular substance

The answer. an ionic compound

Why. The ions are locked in place in the solid and free once it melts or dissolves.

Put the two side by side

Solid ionic: ions present but fixed, so no conduction.
Molten ionic: same ions, now free, so it conducts.

The pattern of when it conducts is the fingerprint of the structure.

Conduction thought to require ions

What it looks like

Graphite or a metal is explained as conducting because it contains ions.

Why it happens

Ionic conduction is met first and becomes the only mechanism available.

A worked example

Question. Why graphite conducts

A common answer. it contains ions

The answer. each carbon bonds to only three others, leaving delocalised electrons free to move

Why. Graphite is pure carbon; there are no ions in it at all.

Put the two side by side

Ionic compounds conduct because ions move, once molten or dissolved.
Metals and graphite conduct because electrons move.

Either charge carrier works. The question is only whether something charged is free to move.

Covalent described as transferring electrons

What it looks like

A covalent bond is defined as electrons being given away rather than shared.

Why it happens

Transfer is the mechanism learned first, in ionic bonding, and it becomes the default.

A worked example

Question. What a covalent bond is

A common answer. electrons are transferred

The answer. a shared pair of electrons between two atoms

Why. Neither non-metal will give an electron up, so sharing is the only way both fill a shell.

Put the two side by side

Ionic: one atom gives, the other takes.
Covalent: both hold the same pair.

Co means together. The word carries the whole definition.

Melting point explained by mass

What it looks like

Magnesium oxide is said to melt higher than sodium chloride because it is heavier.

Why it happens

Heavier feels like it should be harder to pull apart.

A worked example

Question. Why MgO melts higher than NaCl

A common answer. magnesium is heavier

The answer. MgO has 2+ and 2- ions, so the electrostatic attraction is much stronger

Why. The strength of the attraction depends on the charges, not the masses.

Put the two side by side

NaCl: 1+ and 1- ions.
MgO: 2+ and 2- ions, four times the charge product.

For ionic melting points, always look at the charges first.

The wrong bonding type named

What it looks like

Sodium chloride is given covalent, metallic or hydrogen bonding.

Why it happens

Four bonding types are learned together and none of them can be seen.

A worked example

Question. What holds solid sodium chloride together

A common answer. covalent bonding

The answer. ionic bonding

Why. A metal with a non-metal transfers electrons, which makes ions.

Put the two side by side

Metal plus non-metal: ionic.
Non-metal plus non-metal: covalent. Metal alone: metallic.

Look at which side of the table each element comes from. That decides it every time.

Weak forces between molecules confused with the bonds inside them

What it looks like

Graphite is said to have weaker covalent bonds than diamond.

Why it happens

Graphite really is softer, so something about it must be weaker.

A worked example

Question. Why graphite is soft

A common answer. its covalent bonds are weaker

The answer. the layers are held together only by weak forces between them

Why. The covalent bonds within a layer are as strong as those in diamond.

Put the two side by side

Within a layer: strong covalent bonds.
Between layers: weak forces that let the layers slide.

Softness and melting point often come from the weak forces, not from the bonds themselves.

WAJD spots these patterns in your child's answers and names the one behind their wrong answers, instead of just marking them wrong.

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